Morpholine CAS 110-91-8
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Morpholine CAS 110-91-8

Morpholine, also known as 1,4-oxoazacyclohexane, diethylideneimine oxide, colourless alkaline oily liquid with ammonia odour and hygroscopicity, can be volatilized with water vapour, miscible with water, soluble in acetone, benzene, ethyl ether, pentane, methanol, ethanol, carbon tetrachloride, propylene glycol and other organic solvents. Vapour and air to form explosive mixtures, explosion limit 1.8%-15.2% (v/v). Morpholine is a secondary amine, also has both inorganic acid and organic acid properties, can produce salt and amide. Morpholine contains a secondary amine group and has all the typical reaction characteristics of a secondary amine group. It reacts with inorganic acids to form salts, with organic acids to form salts or amides, can undergo alkylation, and can also react with ethylene oxide, ketones, or undergo the Willgerodt reaction. Due to the unique chemical properties of morpholine, it has become one of the fine petrochemicals with important commercial applications, and can be used in the preparation of NOBS, DTOSChemicalbook and MDS and other rubber vulcanisation accelerators, rust inhibitors, corrosion inhibitors, detergents, descaling agents, painkillers, local anaesthetics, sedatives, respiratory system and vascular stimulants, surface activators, Optical bleaching agent, fruit preservative, textile printing and dyeing auxiliaries, etc., in the rubber, medicine, pesticides, dyes, coatings and other industries have a wide range of uses, pharmaceuticals used in the production of morpholino guanidine, viruses, ibuprofen, cough must be, naproxen, dichloroaniline, phenylacetic acid sodium, and many other important drugs. Foreign countries in recent years the rapid development of new polymer monomer acrylic acid morpholine is also worth noting. Acrylic acid morpholine is by the reaction of acrylate and morpholine, the product is a water-soluble monomer, its polymerisation is also water-soluble, so used for the modification of water-based polymers; in addition to a large number of ultraviolet curing resins used for the reaction of the diluent; with the application of the research continues to deepen, many new specific uses continue to be developed, and has become a very rapid development of the polymer monomer.
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  • 110-91-8

  • bosschemical

  • 110-91-8


Morpholine

CAS No. 110-91-8

Alias: 1,4-Oxazinan;1,4-oxazine,tetrahydro-;2H-1,4-Oxazine, tetrahydro-;4H-1,4-Oxazine, tetrahydro-;BASF 238;basf238;Diethylenimide oxide;diethylenimideoxide

Molecular formula:C4H9NO

Molecular weight:87.12

Structural formula:

吗啉 结构式


1.Performance and use:

Colourless absorbent oily liquid. Ammonia odour. Soluble in water and methanol, ethanol, benzene, acetone, ether, glycol and other common solvents.

Used as raw material for medicine, rubber accelerator and fluorescent whitening agent.

Morpholine is the intermediate of fungicide enoymorpholine and flumorpholine and organophosphorus insecticide methidathion.

It is mainly used in the production of rubber vulcanisation accelerator, and also used in the synthesis of surfactants, textile printing and dyeing auxiliaries, pharmaceuticals and pesticides. Morpholine is also used as a catalyst for polymerisation of cis-butadiene, corrosion inhibitor, optical bleach, this product is also a solvent for dyestuffs, resins, waxes, early glue, casein and so on. At present, the world output of morpholine Chemicalbook is 30,000-40,000t/a. The salts of morpholine are also widely used, morpholine hydrochloride (10024-89-2) and so on are the intermediates of organic synthesis; the fatty acid salt of morpholine can be used as the coating agent of the epidermis of fruits or melons and fruits and vegetables, and it can appropriately inhibit the base respiration and prevent the volatilisation of the water and the shrivelling of the epidermis.

Promoter NOBS main raw material, there are used as analytical reagents and resins, waxes, wormwood and other solvents, used in the production of sodium sulfate. Water glass and ultramarine. It is also used in the manufacture of glass. Paper making. Detergent. Soap. Dyes. Synthetic fibres. Leather. Pharmaceutical and ceramic industries. Analytical reagents, e.g. nitrogen determination, dehydrating agents.

Used as analytical reagent and solvent for resins, waxes, casein, wormwood and many dyes.

Morpholine reacts with inorganic acids to form salts, and with organic acids to form salts or amides. It can be alkylated, and also reacts with ethylene oxide, ketone or undergoes Willgerodt reaction.

2.Technical indicators:

Test Items

Specification (%)

Test Results (%)

Assay


99.5min.

99.75%

Boiling point


126-129DC

127.0-129.0

Color


10max.

5

Density


0.999-1.002

1.001

Water content


0.20%max.

0.04%

3. Packaging and storage:

Packaging specification: Packing specification: 25kg/drum, also can be determined according to user's need.

During transportation, it is necessary to protect against sunlight, rain, and high temperatures.

The product should be stored in a cool, dark, ventilated place, away from sources of fire.


4.Safety protection:

Pay attention to labor protection when handling it and avoid contact with skin, eyes, etc.After contact, rinse immediately with plenty of water



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