Lithium Tetrafluoroborate CAS 14283-07-9
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Lithium Tetrafluoroborate CAS 14283-07-9

Lithium tetrafluoroborate is white powder, density: 0.852g/cm3, melting point 293-300℃, and will decompose in contact with wet air or water.
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  • 14283-07-9

  • boss chem

  • 14283-07-9

Lithium tetrafluoroborate

CAS No.14283-07-9


Alias: LITHIUMTETRAFLUOROBORATE;LITHIUMBOROFLUORIDE;Borate(1-),tetrafluoro-,lithium;lithiumfluoborate;Lithiumfluoborate,monohydrate;Chemicalbooklithiumtetrafluoroborate,anhydrous;Lithiumtetrafluoroborate,ultradry,99.997%(metalsbasis);LITHIUMTETRAFLUOROBORATEFORSYNTHESIS

Molecular formula: BF4Li

Relative molecular mass: 93.75

Structural formula:

14283-07-9


1. Performance and use:

Catalyst in organic synthesis; electrolyte for lithium ion batteries.

Lithium tetrafluoroborate is a mild Lewis acid for Diels-Alder reactions. Catalyst for mild and efficient aminolysis of oxiranes. It is a reagent used in the preparation of rechargeable lithium-ion batteries.

Lithium tetrafluoroborate (LiBF4) finds application as electrolyte material in lithium ion batteries (LIBs). However, the presence of trace amount of water in LiBF4 causes its hydrolysis which leads to HF generation and destruction of the battery electrodes. Our LiBF4 contains < 100 ppm of water and is well suited for applications in LIBs.


2. Technical indicators

Lithium tetrafluoroborate Basic information
Product Name: Lithium tetrafluoroborate
CAS: 14283-07-9
MF: BF4Li
MW: 93.75
EINECS: 238-178-9
Mol File: 14283-07-9.mol
Lithium tetrafluoroborate Chemical Properties
Melting point 293-300 °C (dec.) (lit.)
density 0.852 g/mL at 25 °C
Fp 6 °C
storage temp. Store below +30°C.
form powder
color White to off-white
Specific Gravity 1
PH 2.88
Water Solubility SOLUBLE
Sensitive Hygroscopic
Merck 145,543

3. Usage

Dissolve it in THF just below its solubility, filter from insoluble material and evaporate it to dryness in a vacuum below 50o. Wash the residue with dry Et2O, and pass dry N2 gas over the solid and finally heat it in an oven at 80-90o. Its solubility in Et2O is 1.3g in 100mL at 25o; in THF it is 71g in 100mL at 25o. It is hygroscopic and is an IRRITANT.



Related keywords:


Lithium Tetrafluoroborate

14283-07-9

Lithium Tetrafluoroborate price

Lithium ion battery electrolyte



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